Bis[2-(1H-benzimidazol-2-yl)phenolato-κ2 N 3,O]cobalt(II) dimethyl­formamide disolvate

نویسندگان

  • Feigang He
  • Yun Xi
  • Jun Li
  • Fengxing Zhang
چکیده

In the crystal structure of the title compound, [Co(C(13)H(9)N(2)O)(2)]·2C(3)H(7)NO, the Co(II) ion is four-coordinated by two N atoms and two O atoms from two deprotonated 2-(1H-benzimidazol-2-yl)phenol ligands in a distorted tetra-hedral geometry. The dimethyl-formamide solvent mol-ecules are found inside a two-dimensional network structure formed by inter-molecular N-H⋯O hydrogen bonds linking the mol-ecules.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Bis{2-[2-(1H-indol-3-yl)ethyl­imino­meth­yl]phenolato-κ2 N,O}nickel(II) N,N-dimethyl­formamide disolvate

The Ni atom in the title compound, [Ni(C(17)H(15)N(2)O)(2)]·2C(3)H(7)NO, lies on a twofold rotation axis. It is N,O-chelated by the deprotonated Schiff base 2-[2-(1H-indol-3-yl)ethyl-imino-meth-yl]phenolate ligand in a square-planar coordination environment. The mol-ecule is linked to a solvent mol-ecule by an indole-dimethyl-formamide N-H⋯O hydrogen bond.

متن کامل

Bis[1,3-bis­(1-ethyl-1H-benzimidazol-2-yl)-2-oxapropane]­cadmium(II) dipicrate dimethyl­formamide disolvate

In the title compound, [Cd(C(20)H(22)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Cd(II) ion is coordinated by four N atoms and two O atoms from two tridentate 1,3-bis-(1-ethyl-1H-benzimid-azol-2-yl)-2-oxapropane ligands in a distorted octa-hedral environment.

متن کامل

Bis{μ-1,3-bis­[(benzimidazol-1-yl)meth­yl]benzene-κ2 N 3:N 3′}bis­[dichloridozinc(II)] dimethyl­formamide disolvate

In the title compound, [Zn(2)Cl(4)(C(22)H(18)N(4))(2)]·2C(3)H(7)NO, the 1,3-bis-[(benzimidazol-1-yl)meth-yl]benzene ligand bridges two ZnCl(2) units, forming a centrosymmetric dinuclear mol-ecule. The Zn(II) atom shows a distorted tetra-hedral coordination within a Cl(2)N(2) donor set.

متن کامل

Bis[2,6-bis­(1H-benzimidazol-2-yl)pyridine]­nickel(II) dipicrate dimethyl­formamide disolvate

In the title compound, [Ni(C(19)H(13)N(5))(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Ni(II) ion is coordinated by two tridentate 2,6-bis-(1H-benzimidazol-2-yl)pyridine ligands in a distorted octa-hedral geometry. In the crystal structure, the picrate anions and solvent dimethyl-formamide (DMF) mol-ecules are connected to the cation via inter-molecular N-H⋯O hydrogen bonds. Further stabilization...

متن کامل

Bis[(1-methyl-1H-benzimidazol-2-yl)methanol-κ2 N 3,O]bis­(thio­cyanato-κN)cobalt(II) methanol solvate

In the mononuclear title complex, [Co(NCS)(2)(C(9)H(10)N(2)O)(2)]·CH(3)OH, the cobalt(II) ion is surrounded by two (1-methyl-1H-benzimidazol-2-yl)methanol bidentate ligands and two thio-cyanate ligands, and exhibits a distorted octa-hedral coordination by four N atoms and two O atoms. The structure is consolidated by hydrogen bonds between the organic ligand, thio-cyanate anion and the uncoordi...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008